Journal
TETRAHEDRON LETTERS
Volume 54, Issue 3, Pages 249-251Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.11.011
Keywords
Trifluoromethylation; Metal-free; Hypervalent iodine
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Funding
- National Natural Science Foundation of China [21072028, 20832008]
- National Basic Research Program of China [2012CB21600]
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A PhI(OAc)(2)-mediated oxidative trifluoromethylation of arenes with CF3SiMe3 under metal-free conditions has been described. This protocol precludes the need of substrate pre-functionalization and metal catalysts, enabling a direct access to a series of trifluoromethylated arenes and heterocycles containing common functional groups in moderate and good yields. (c) 2012 Elsevier Ltd. All rights reserved.
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