Journal
TETRAHEDRON LETTERS
Volume 54, Issue 3, Pages 262-266Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.11.017
Keywords
Amine; Protic ionic liquid; N-formylation; Formamides; Catalysis; Formic acid
Categories
Funding
- Department of Science and Technology (DST), Govt. of India [SR/S1/OC-49/2010]
- Canadian Institute for Health Research, Canada
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A fast, efficient and simple route for the N-formylation of amines has been developed by treating amines with 85% formic acid at 70 degrees C in the presence of 5 mol % of protic ionic liquid as catalyst under solvent-free condition. This method provides a green and much improved protocol over the existing methods. (C) 2012 Elsevier Ltd. All rights reserved.
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