Journal
TETRAHEDRON LETTERS
Volume 54, Issue 35, Pages 4785-4788Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.06.135
Keywords
Deoxyvitisins; Vitisins; Deoxyanthocyanidins; Aldehydes; NMR; Mass spectrometry
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Funding
- FCT (Fundacao para a Ciencia e Tecnologia) [SFRH/BD/68736/2010, PTDC/QUI-QUI/117996/2010]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/68736/2010] Funding Source: FCT
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The chemical synthesis of new deoxyvitisins (pyrano-3-deoxyanthocyanidins) is reported herein. Three different types of compounds were synthesised from the reaction between two deoxyanthocyanidins (deoxypeonidin and deoxymalvidin) and pyruvic acid, vinyloxy-trimethylsilane and acetone-1,3-dicarboxylic acid. The structure of the new compounds has been characterised by means of visible, MS and NMR spectroscopies. (C) 2013 Elsevier Ltd. All rights reserved.
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