Journal
TETRAHEDRON LETTERS
Volume 54, Issue 34, Pages 4551-4554Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.06.080
Keywords
Phialophora spp.; Tetracyclic altenusin; Xinshengin
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Funding
- Ministry of Science and Technology of China [2009CB522300, 2012ZX09301002-003]
- Natural Science Foundation of China [81202441]
- Guangdong Natural Science Funds for Distinguished Young Scholar [S2013050014287]
- program for New Century Excellent Talents in University from the Ministry of Education of China [NCET-10-0120]
- high-performance computing platform of Jinan University
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Xinshengin (1), the first tetracyclic altenusin with an unprecedented altenuene/tetrahydrofuran-fused skeleton core, has been obtained from cultures of an endolichenic fungal strain Phialophora spp. (No. 39-1-5-1), along with a new compound, phialophoriol (2), and a known compound, altenusin (3). The structures with absolute configurations of 1 and 2 were elucidated by analysis of NMR and quantum chemical ECD calculation. (C) 2013 Elsevier Ltd. All rights reserved.
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