Journal
TETRAHEDRON LETTERS
Volume 54, Issue 10, Pages 1205-1207Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.12.059
Keywords
Acylation; Anilide; Cross-coupling; Palladium-catalyzed; Toluene
Categories
Funding
- National Natural Science Foundation of China [30900959, 20702051]
- Key Innovation Team of Science and Technology in Zhejiang Province [2010R50018-06]
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Direct oxidative ortho-acylation reaction of anilides with toluene derivatives in the presence of palladium acetate using tert-butyl hydroperoxide as an oxidant was developed. A broad range of diaryl ketones was obtained in good to excellent yields (up to 95%). The plausible mechanism was also proposed. (C) 2012 Elsevier Ltd. All rights reserved.
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