4.4 Article

An addition of benzylic sp3 C-H to electron-deficient olefins

Journal

TETRAHEDRON LETTERS
Volume 54, Issue 8, Pages 858-860

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.11.100

Keywords

Benzylic sp3 C-H activation; Electron-deficient olefins; Catalyst free; Aza-ene reaction

Funding

  1. National Natural Science Foundation of China [21172120, 20902050]

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An addition of benzylic sp3 C-H to electron-deficient olefins has been developed. This reaction provides a new method for the benzylic C-H bond functionalization of azaarenes without using any catalyst and additives. (C) 2012 Elsevier Ltd. All rights reserved.

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