4.4 Article

A mild and efficient protocol for the ipso-hydroxylation of arylboronic acids

Journal

TETRAHEDRON LETTERS
Volume 54, Issue 14, Pages 1821-1823

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.01.079

Keywords

Phenols; Aryl boronic acid; Acidic alumina; Hydrogen peroxide; Hydroxylation

Funding

  1. Department of Science and Technology, New Delhi [SR/FT/CS-0098/2009]
  2. University Grants Commission, New Delhi [41-254/2012 (SR)]
  3. Department of Science and Technology

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An ipso-hydroxylation of arylboronic acids to phenols using aqueous H2O2 as oxidant and acidic alumina as catalyst has been reported in this study. The reusability of the catalyst is also investigated. (C) 2013 Elsevier Ltd. All rights reserved.

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