Journal
TETRAHEDRON LETTERS
Volume 54, Issue 8, Pages 865-870Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.11.101
Keywords
Glycosylation; ortho-Alkynylbenzoates; Iodine; Chemoselective; One-pot
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Funding
- CSIR
- DBT, Govt. of India
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A novel and high yielding glycosylation protocol with glycosyl ortho-alkynylbenzoates as donors and iodine as promoter is described. The donors are stable and can be chemoselectively activated in the presence of thioethyl and thiophenyl glycosides. The application of this methodology in one-pot consecutive glycosylation reaction is described. (C) 2012 Elsevier Ltd. All rights reserved.
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