Journal
TETRAHEDRON LETTERS
Volume 54, Issue 2, Pages 176-178Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.10.121
Keywords
[2,2]Paracyclophane; Azocompounds; Circular dichroism; Planar chirality
Categories
Funding
- MEXT, Japan [19050013, 24550142]
- JSPS, Japan
- Grants-in-Aid for Scientific Research [24550142, 19050013] Funding Source: KAKEN
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We designed and synthesized a new prochiral molecule in which two azobenzene moieties were embedded in [2,2]paracyclophane and showed the chirality induction by E-Z photoisomerization. We also demonstrated the on/off switching of asymmetry by irradiation and reflux respectively. (C) 2012 Elsevier Ltd. All rights reserved.
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