4.4 Article

Pd(OAc)2-catalyzed ligand-free cyanation of diaryliodonium salts with K4[Fe(CN)6]

Journal

TETRAHEDRON LETTERS
Volume 53, Issue 51, Pages 6954-6956

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.10.036

Keywords

Diaryliodonium salts; Pd(OAc)(2); Cyanation reaction; K-4[Fe(CN)(6)]

Funding

  1. Foundation of Chang Zhou Municipal Bureau of Science and Technology [KYZ1102100C]
  2. Priority Academic Program Development of Jiangsu Higher Education Institutions

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An effective palladium-catalyzed cyanation of diaryliodonium salts with K-4[Fe(CN)(6)] in DMF at 130 degrees C has been developed, affording the aryl nitriles in high yields via ligand-free process. (C) 2012 Elsevier Ltd. All rights reserved.

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