Journal
TETRAHEDRON LETTERS
Volume 53, Issue 2, Pages 232-234Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.11.025
Keywords
Selenolate; GPx mimetics; Thiols; Peroxide; Oxidation
Categories
Funding
- Fondazione Cassa di Risparmio di Perugia, Ricerca di Base [2010.011.0415]
- M.I.U.R. (Ministero Italian Universita e Ricerca)
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The ability of PhSeZnCl 1 to catalyze the oxidation of thiols to disulfides has been evaluated and correlated to a catalytic GPx-like activity. The first evidence that vinyl phenylselenides can promote the oxidation of thiols reducing hydrogen peroxide through the formation of a selenoxide intermediate is also reported. (C) 2011 Elsevier Ltd. All rights reserved.
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