Journal
TETRAHEDRON LETTERS
Volume 53, Issue 34, Pages 4609-4612Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.06.099
Keywords
Neutral guest recognition; Pillararenes; Alkanediamines; Click chemistry; Supramolecular chemistry
Categories
Funding
- National Natural Science Foundation of China [20902057, 21002061, 21142012]
- Shanghai Municipal Education Commission [J50101]
- Key Laboratory of Synthetic Chemistry of Natural Substances, Chinese Academy of Sciences
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A fully functionalized pillar[5]arene was synthesized by 'click chemistry' and the possible synthetic strategies have been discussed. The host showed effective binding affinities toward neutral alkanediamines (K-a > 10(3) M-1), which are much larger than those observed for simple methyl-substituted pillar[5]arene. (C) 2012 Elsevier Ltd. All rights reserved.
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