Journal
TETRAHEDRON LETTERS
Volume 53, Issue 25, Pages 3178-3180Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.04.048
Keywords
Amides; Gold; Heterogeneous catalysis; Amines; Alcohols
Categories
Funding
- National Natural Science Foundation of China [21073208]
- Chinese Academy of Sciences
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Hydrotalcite-supported nano-gold (Au/HT) was found to be a highly efficient heterogeneous catalyst for the dehydrogenative synthesis of amide from alcohol and amine. Amines and alcohols with different structures could be converted into the amides under mild reaction conditions with up to 98% isolated yields. Mechanism exploration suggested that ester might be the reaction intermediate. (C) 2012 Elsevier Ltd. All rights reserved.
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