Journal
TETRAHEDRON LETTERS
Volume 53, Issue 15, Pages 2005-2008Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.02.032
Keywords
Visible light; Photoredox catalysis; Trifluoromethylation; Heterocycles; Ruthenium
Categories
Funding
- National Research Foundation of Korea (NRF) [NRF-2011-0013118]
- National Research Foundation of Korea [2011-0013118] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A method has been developed for the visible light-induced trifluoromethylation of heterocyclic compounds. A variety of electron-rich heterocycles were transformed into trifluoromethylated products by using CF3I as the trifluoromethyl radical source and Ru(bpy)(3)Cl-2 as the photocatalyst under mild reaction conditions. This operationally simple and eco-friendly process can introduce trifluoromethyl groups without prefunctionalization. (C) 2012 Elsevier Ltd. All rights reserved.
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