4.4 Article

A general and selective zinc-catalyzed oxidation of sulfides to sulfoxides

Journal

TETRAHEDRON LETTERS
Volume 53, Issue 33, Pages 4328-4331

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.06.003

Keywords

Zinc catalyst; Sulfide; Sulfoxide; Oxidation; H2O2

Funding

  1. state of Mecklenburg-Vorpommem
  2. Bundesministerium fur Bildung und Forschung (BMBF)

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A general zinc-catalyzed oxidation of sulfides to sulfoxides has been developed. All the reactions proceeded at room temperature. Hydrogen peroxide was used as a green oxidant. Twenty-one examples of sulfoxides were prepared in moderate to excellent yields. (C) 2012 Elsevier Ltd. All rights reserved.

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