Journal
TETRAHEDRON LETTERS
Volume 53, Issue 47, Pages 6380-6382Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.09.032
Keywords
Sonnerlactones; Antiproliferative; Asymmetric allylation; Alder-Rickert reaction; Mitsunobu macrolactonization
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Funding
- CSIR, New Delhi, India
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The stereoselective synthesis of (3R,5R)-sonnerlactone (1) and (3R,55)-sonnerlactone (2) has been accomplished starting from L-aspartic acid. Our strategy involves asymmetric allylation, Alder-Rickert reaction and Mitsunobu macrolactonization as the key steps. (C) 2012 Elsevier Ltd. All rights reserved.
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