Journal
TETRAHEDRON LETTERS
Volume 53, Issue 49, Pages 6646-6649Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.09.083
Keywords
Copper catalysis; Trifluoromethylated acetylenes; Trifluoromethylation; Alkynyltrifluoroborates
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Funding
- National Natural Science Foundation of China [21072030]
- Fuzhou University [022318]
- King Abdullah University of Science and Technology
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A new method for the synthesis of trifluoromethylated acetylenes is developed which involves the copper-catalyzed trifluoromethylation of alkynyltrifluoroborates with an electrophilic trifluoromethylating reagent. This method offers significant advantages such as efficiency and mild and base-free reaction conditions. A plausible mechanism is proposed. (c) 2012 Published by Elsevier Ltd.
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