4.4 Article

NaIO4-NaN3-mediated diazidation of styrenes, alkenes, benzylic alcohols, and aryl ketones

Journal

TETRAHEDRON LETTERS
Volume 53, Issue 32, Pages 4195-4198

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.05.140

Keywords

Alkenes; Aryl ketones; Sodium periodate; Vicinal diazides; Geminal diazides

Funding

  1. CSIR
  2. DST New Delhi [SR/S1/OC-67/2010]

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Sodium periodate and sodium azide combination has been found to be an excellent reagent system suitable for the direct diazidation of styrenes, alkenes, benzylic alcohols, and aryl ketones to produce the corresponding vicinal and geminal diazides respectively in high yields under mild reaction conditions. (C) 2012 Elsevier Ltd. All rights reserved.

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