Journal
TETRAHEDRON LETTERS
Volume 53, Issue 29, Pages 3735-3738Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.04.118
Keywords
(R)-Epichlorohydrin; Epoxidation; Lactonization; Ring closing metathesis (RCM); Grubb's catalyst
Categories
Funding
- CSIR-UGC
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A first total synthetic route has been reported for the synthesis of Phomolide G and H. The syntheses of fragments were initiated from commercially available and inexpensive starting material (R)-epichlorohydrin. The synthesis involves a key Sharpless epoxidation, stereoselective epoxide opening, lactonization and ring closing metathesis (RCM). (C) 2012 Elsevier Ltd. All rights reserved.
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