Journal
TETRAHEDRON LETTERS
Volume 53, Issue 22, Pages 2769-2772Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.03.107
Keywords
Trifluoromethylation; Umemoto's reagent; Terminal alkynes; Copper-catalyzed
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Funding
- National Key Basic Research Program of China [2012CB215305, 2012CB215306]
- National Natural Science Foundation of China [21172209]
- Chinese Academy of Science [KJCX2-EW-J02]
- Fundamental Research Funds for the Central Universities
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A copper-catalyzed method for trifluoromethylation of terminal alkynes with Umemoto's reagent has been developed. The reaction is conducted at room temperature and shows good tolerance to a variety of functional groups. (C) 2012 Published by Elsevier Ltd.
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