4.4 Article

Efficient synthesis of pentakis- and tris(pyridine) ligands

Journal

TETRAHEDRON LETTERS
Volume 53, Issue 1, Pages 54-55

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.10.131

Keywords

Tripodal ligand; Tetrapodal pentadentate ligand; Oligopyridines; Ligand design; Nucleophilic substitution

Funding

  1. Deutsche Forschungsgemeinschaft [SFB 658]
  2. Chemetall GmbH
  3. Studienstiftung des Deutschen Volkes

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A variety of substituted tris(pyridyl) frameworks, as well as a pentakis(pyridine) system, are conveniently accessible in a one-pot synthesis, which consists of two sequential nucleophilic aromatic substitutions, employing substituted pyridine precursors. (C) 2011 Elsevier Ltd. All rights reserved.

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