4.4 Article

Total synthesis of (+)-pericosine B and (+)-pericosine C and their enantiomers by using the Baylis-Hillman reaction and ring-closing metathesis as key steps

Journal

TETRAHEDRON LETTERS
Volume 53, Issue 2, Pages 132-136

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.10.135

Keywords

Pericosine; Carbasugars; Baylis-Hillman reaction; Ring closing metathesis; Hoveyda-Grubbs catalyst

Funding

  1. Department of Science and Technology, New Delhi [JCB/SR/S2/JCB-26/2010]
  2. Council of Scientific and Industrial Research, New Delhi [01(2298)/09/EMR-II]

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A simple and divergent route for the total synthesis of pericosine B and pericosine C and their enantiomers from D-ribose by using the Baylis-Hillman reaction and ring-closing metathesis reactions as key steps has been described. (C) 2011 Elsevier Ltd. All rights reserved.

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