Journal
TETRAHEDRON LETTERS
Volume 53, Issue 36, Pages 4862-4865Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.06.134
Keywords
Ruthenium catalyst; N-H insertion reaction; Diazoacetamide; alpha-Aminoamide
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Funding
- Japan Society for the Promotion of Science [23550179]
- Grants-in-Aid for Scientific Research [23550179] Funding Source: KAKEN
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An efficient protocol for the preparation of alpha-aminoamides was developed via the Ru(II)-dm-Pheox catalyzed N-H insertion reaction of various diazoacetamides with several amines, including aniline. This catalytic N-H insertion reaction was also applied to the synthesis of 2-(2-methylquinolin-4-ylamino)-N-phenylacetamide, a potential antileishmanial agent. (C) 2012 Elsevier Ltd. All rights reserved.
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