Journal
TETRAHEDRON LETTERS
Volume 53, Issue 51, Pages 6968-6971Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.10.044
Keywords
Deep-Eutectic-Solvents; Separations; Alcohols; Esters; Kinetic resolutions
Categories
Funding
- DFG training group [1166 'BioNoCo']
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Deep-Eutectic-Solvents (DES) were assessed for the separation of alcohol-ester mixtures, for example those typically obtained from catalytic kinetic resolutions of racemic alcohols. DES can efficiently dissolve molecules containing hydrogen-bond-donors (alcohols), whereas esters remain as second phase. By using this concept, tedious separation chromatographic steps may be easily overcome with bio-based non-hazardous solvents. (C) 2012 Elsevier Ltd. All rights reserved.
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