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Palladium-catalyzed desulfitative addition of sodium sulfinates with α,β-unsaturated carbonyl compounds

TETRAHEDRON LETTERS (2012)

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Journal

TETRAHEDRON LETTERS
Volume 53, Issue 33, Pages 4347-4350

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.06.026

Keywords

Addition; Desulfination; Palladium; Sulfinic acids

Categories

Chemistry, Organic

Funding

  1. National Natural Science Foundation of China [21172185, 20902076]
  2. Hunan Provincial Natural Science Foundation of China [11JJ1003]
  3. New Century Excellent Talents in University from Ministry of Education of China [NCET-11-0974]
  4. Scientific Research Foundation for Returned Scholars, Ministry of Education of China [2011-1568]

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A palladium-catalyzed desulfitative conjugate addition of sodium sulfinates with alpha,beta-unsaturated carbonyl compounds is described. The reaction showed very good selectivity and tolerated a wide range of functionalities under an atmosphere of argon. (C) 2012 Elsevier Ltd. All rights reserved.

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