Journal
TETRAHEDRON LETTERS
Volume 53, Issue 4, Pages 416-418Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.11.061
Keywords
Transfer hydrogenation; Reduction; Imine; Benzothiazoline; Reductive amination
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
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A benzothiazoline bearing 4-carboxyphenyl group at 2-position was developed as an efficient hydrogen donor for the transfer hydrogenation reaction. Introduction of the carboxyl group significantly facilitated the removal of the residual benzothiazoline and benzothiazole by washing with aqueous basic solution. The present approach provides a convenient and straightforward access to various amines with broad substrate scope and in good yields. (C) 2011 Elsevier Ltd. All rights reserved.
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