4.4 Article

Fluorescent: chemosensor based-on naphthol-quinoline for selective detection of aluminum ions

Journal

TETRAHEDRON LETTERS
Volume 52, Issue 43, Pages 5581-5584

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.08.045

Keywords

Fluorescent chemosensor; Aluminum ion sensing; Naphthol; Quinoline; Selective binding

Funding

  1. National Research Foundation of Korea
  2. Korean Government [2009-0087304]
  3. Korean Science & Engineering Foundation [2009-0074066]
  4. Converging Research Center through the National Research Foundation of Korea (NRF)
  5. Ministry of Education, Science and Technology [2009-0082832]
  6. BK21
  7. National Research Council of Science & Technology (NST), Republic of Korea [2E2214] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  8. National Research Foundation of Korea [2010-50247, 2009-0074066, 2009-0087304] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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In this study, an assay to quantify the presence of aluminum ions with a receptor containing naphthol and quinoline moieties was developed using a turn-on fluorescence enhancement approach. Upon treatment with aluminum ions, the fluorescence of the receptor was enhanced at 510 nm due to the formation of a complex between the ligand and aluminum ions at room temperature. As the concentration of Al3+ was increased, the fluorescence gradually increased. Other metal ions, such as K+, Ag+, Ca2+, Mg2+, Zn2+, Mn2+, Co2+, Ni2+, Cu2+, Cd2+, Cr3+, Fe3+, In3+, had no significant effect on the fluorescence. (C) 2011 Published by Elsevier Ltd.

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