Journal
TETRAHEDRON LETTERS
Volume 52, Issue 25, Pages 3186-3188Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.03.015
Keywords
Trigonoine A; Trigonoine B; beta-Carboline alkaloid; Trigonostemon lii
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Funding
- Ministry of Science and Technology of China [2009CB940900, 2009CB522300]
- National Natural Science Fund of China [21072199, 30830114]
- Natural Science Fund of Yunnan Province [2009CD112]
- Foundation of Chinese Academy of Sciences
- Yong Academic and Technical Leader Raising Foundation of Yunnan Province [2010CI047]
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Two novel alkaloids, trigonoine A containing a 2,8-diazabicyclo[3.3.1]nonane ring system and trigonoine B formed by a combination of a 2,3-dihydroquinolin-4-one and 3H-pyrrolo[2,3-c]quinoline rearranged from B-carboline skeleton were isolated from the leaves of Trigonostemon lii. Their structures were elucidated by 10 and 20 NMR spectroscopic methods. (C) 2011 Elsevier Ltd. All rights reserved.
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