Journal
TETRAHEDRON LETTERS
Volume 52, Issue 38, Pages 4848-4853Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.07.028
Keywords
BODIPY; Push-pull; Cycloaddition; Tetracyano; Fluorescence; Electrochemistry
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Funding
- CNRS
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A series of BODIPY bridged push-pull chromophores were prepared by a sequence of reactions involving: i) cross-coupling reactions promoted by palladium complexes; ii) Knoevenagel condensation leading to dicyano derivatives; iii) [2+2] cycloaddition. The last reaction is regioselective, providing mono-derivatives with anisole substituents. With dimethylaminophenyl donor groups, double addition is feasible, providing highly colored dyes displaying remarkable electrochemical properties. (C) 2011 Elsevier Ltd. All rights reserved.
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