4.4 Article

Synthesis and reaction of phthaloyl peroxide derivatives, potential organocatalysts for the stereospecific dihydroxylation of alkenes

Journal

TETRAHEDRON LETTERS
Volume 52, Issue 20, Pages 2540-2542

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.03.005

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Funding

  1. Robert A. Welch Foundation [F-1694]
  2. University of Texas at Austin

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To improve the synthesis and reactivity of phthaloyl peroxide derivatives a method has been developed using sodium percarbonate and phthaloyl chlorides. The reactions of the new phthaloyl peroxide derivatives with trans-stillbene as well as the improved reactivity of 3,4-dichlorophthaloyl peroxide with a variety of alkenes are reported. (C) 2011 Elsevier Ltd. All rights reserved.

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