Journal
TETRAHEDRON LETTERS
Volume 52, Issue 12, Pages 1334-1338Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.01.059
Keywords
Palladium; Alkylation; Alcohol; Amine
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Funding
- National Natural Science Foundation of China [21073208]
- CAS
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An iron oxide immobilized palladium catalyst was prepared for the N-alkylation of amines with alcohols under base and organic ligand free conditions. Applying the optimized reaction conditions, the coupling reactions of amines and alcohols with various structures could be realized with up to 99% isolated yields. The catalysts were studied by XRD, BET, and XPS and the mechanism was studied by DFT calculations. (C) 2011 Elsevier Ltd. All rights reserved.
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