Journal
TETRAHEDRON LETTERS
Volume 52, Issue 47, Pages 6234-6237Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.09.064
Keywords
Organocatalyst; Allylic alcohol; Morita-Baylis-Hillman reaction; Bis(thiourea)
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Newly-developed bis(thiourea) 1d was found to be an efficient organocatalyst for the Morita-Baylis-Hillman reaction. High enantioselectivities were obtained in the reaction of 2-cyclohexen-1-one with both aromatic aldehydes (up to 84% ee) and aliphatic aldehydes (up to 96% ee). (C) 2011 Elsevier Ltd. All rights reserved.
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