Journal
TETRAHEDRON LETTERS
Volume 52, Issue 47, Pages 6220-6222Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.09.099
Keywords
Metal-organic framework; Biginelli reaction; Heterogeneous catalyst; Solvent-free conditions; Green reactions
Categories
Funding
- Welch Foundation [AX-1730, AX-1593]
- National Institutes of Health-National Institute of General Medical Sciences [SC1GM082718]
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Two new Zn(II) and Cd(II) MOFs have been synthesized. These MOFs have been applied as heterogeneous catalysts for the green synthesis of a variety of dihydropyrimidinone derivatives through the Biginelli reaction and the desired products were obtained in high yields with short reaction time under mild solvent-free conditions. Moreover, the MOF catalysts may be readily recovered after the reaction and reused for many cycles. (C) 2011 Elsevier Ltd. All rights reserved.
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