Journal
TETRAHEDRON LETTERS
Volume 52, Issue 30, Pages 3856-3860Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.05.072
Keywords
Dihydrobenzofuran lignans; Radical cross-coupling reaction; Horseradish peroxidase
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Funding
- University of Milan-Bicocca
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The possibility to afford by a biomimetic reaction 'unnatural' products, which could offer a better bioactivity profile than natural analogues, is outlined and the first applications to the synthesis of lignans and related compounds have been reported. Here we describe the synthesis of new heterodimers, having a phenylcoumaran skeleton, by horseradish peroxidase catalyzed cross-coupling reactions of methyl esters of substituted hydroxycinnamic acids. (C) 2011 Elsevier Ltd. All rights reserved.
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