Journal
TETRAHEDRON LETTERS
Volume 52, Issue 12, Pages 1395-1397Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.01.104
Keywords
Enantioselective hydrogenation; Supercritical carbon dioxide; Imines; Iridium
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Funding
- RFBR [09-03-12104-ofi_m]
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A series of chiral phosphite-type ligands has been evaluated in the iridium-catalyzed asymmetric hydrogenation of acyclic arylimines in supercritical CO2. High reactivities (100% conversion in 50-120 min) and enantioselectivities (up to 95%) were obtained. (C) 2011 Elsevier Ltd. All rights reserved.
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