Journal
TETRAHEDRON LETTERS
Volume 52, Issue 13, Pages 1441-1443Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.01.044
Keywords
meso-Tetraarylporphyrins; Selenium dioxide; Heterogeneous oxidation; Porphyrinogen oxidation; Porphyrins
Categories
Funding
- Fundacao Araucaria
- CNPq
- PRONEX-Carboidratos
- REUNI
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The oxidative step of the two-step, one-flask synthesis of meso-tetraarylporphyrins is herein conducted with heterogeneous oxidant SeO2 instead of the usual quinones DDQ or p-chloranil. Evaluation of BF3O(Et)(2) or I-2 amount for the condensation of the first step combined with the excess of SeO2 defined porphyrin synthesis conditions employing benzaldehydes and pyrrole (or 5-phenyldipyrromethane) as starting materials. The simplicity of the workup, allied with reaction mild conditions, makes this method a good option for the synthesis of this kind of compound. (c) 2011 Elsevier Ltd. All rights reserved.
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