Journal
TETRAHEDRON LETTERS
Volume 52, Issue 11, Pages 1202-1204Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.01.036
Keywords
Dimethyldioxirane; Furan; Lactone; Oxidation; Natural product synthesis
Categories
Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Department of Education of Quebec (FQRNT)
- FQRNT Centre in Green Chemistry and Catalysis (CGCC)
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The first synthesis of yangjinhualine A, a recently isolated alpha,beta-disubstituted gamma-hydroxybutenolide from the Chinese medicinal herb Datura mete! L., has been accomplished in concise, entirely regiocontrolled fashion through the combined use of Suzuki-Miyaura cross-coupling and 2-silyloxyfuran oxyfunctionalization. (C) 2011 Elsevier Ltd. All rights reserved.
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