Journal
TETRAHEDRON LETTERS
Volume 52, Issue 6, Pages 692-695Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.12.004
Keywords
Aerobic oxidation; Zinc catalyst; Molecular oxygen; Kinetic resolution; Enantioselective oxidation
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Funding
- DST, New Delhi [SR/S1/OC-06/2008]
- UGC, New Delhi
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Zn(II)-DABCO complex is used as an efficient catalyst for the aerobic oxidation of benzoins to benzils in the presence of molecular oxygen. Usage of chiral zinc complex as catalyst resulted in enantioselective oxidative kinetic resolution of racemic benzoin to yield enantiomerically enriched benzoins. (C) 2010 Elsevier Ltd. All rights reserved.
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