Journal
TETRAHEDRON LETTERS
Volume 52, Issue 8, Pages 932-935Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.12.068
Keywords
Isoselenocyanates; Selective synthesis; Selenoheterocycles
Categories
Funding
- National Natural Science Foundation of China [20906083]
- Natural Science Foundation of Zhejiang Province [Y40900488]
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An efficient and regioselective synthesis of 2-imino-1,3-selenazolidin-4-ones and 2-amino-1,3,4-selenadiazin-5-ones was achieved via one-pot reaction of isoselenocyanates, hydrazines, and ethyl chloroacetate or chloroacetyl chloride, respectively. Plausible mechanisms for these transformations were given. (C) 2010 Elsevier Ltd. All rights reserved.
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