☆ 4.4 Article

Facile synthesis of γ-alkenylbutenolides from Baylis-Hillman adducts: consecutive in-mediated Barbier allylation, PCC oxidation, isomerization, and Zn-mediated Barbier allylation

TETRAHEDRON LETTERS (2011)

Get Full Text
Add to Collection

Journal

TETRAHEDRON LETTERS
Volume 52, Issue 49, Pages 6545-6549

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.09.125

Keywords

gamma-Alkenylbutenolides; Baylis-Hillman adducts; Indium; Zinc; Barbier reaction

Categories

Chemistry, Organic

Funding

  1. National Research Foundation of Korea
  2. Korean Government [2011-0002570]

Ask authors/readers for more resources

Protocol

Community support

Reagent

Community support

Alkenylbutenolides were synthesized regioselectively in good to moderate yields from Baylis-Hillman adducts via a consecutive indium-mediated Barbier type reaction between Baylis-Hillman bromide and aldehyde, PCC oxidation of the homoallylic alcohol, double bond isomerization, and zinc-mediated Barbier type alkenylation protocol. (C) 2011 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available
Webinars Posters Questions Hubs Funding Journals Papers Connect Collections Reviewers About Us FAQs Mobile App Privacy Policy Terms of Use
© Peeref 2019-2024. All rights reserved.