Journal
TETRAHEDRON LETTERS
Volume 52, Issue 50, Pages 6709-6712Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.09.134
Keywords
Cryptophycins; Cyclic depsipeptides; Prins cyclization; Olefin rearrangement; Grignard reaction
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Funding
- CSIR New Delhi
- DST
- King Saud University for Global Research Network for Organic Synthesis (GRNOS)
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A stereoselective synthesis of fragment A of cryptophycin is achieved utilizing the versatile Prins cyclization. Subsequently, the total synthesis of cryptophycin-24 (arenastatin A) has been accomplished by coupling it with the depsipeptide subunit. (C) 2011 Elsevier Ltd. All rights reserved.
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