Journal
TETRAHEDRON LETTERS
Volume 52, Issue 49, Pages 6655-6658Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.10.059
Keywords
Ferrocene; Nitroxide radical; Crystal structure; Magnetic property; Redox property; Secondary battery
Categories
Funding
- University of Hyogo
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Several ferrocene derivatives (1-6) carrying nitroxide radical were prepared as dual redox compounds. They have distorted molecular structures and exhibit oxidation potentials based on both ferrocene and nitroxide groups except 4. The multi-step charge-discharge processes are discriminated for mono-substituted derivatives with the first discharge capacity up to 400 Ah kg(-1) for imino-derivative 3, while relatively characterless profiles are observed for bis-substituted derivatives 4 and 6 with capacity over 300 Ah kg(-1). (C) 2011 Elsevier Ltd. All rights reserved.
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