Journal
TETRAHEDRON LETTERS
Volume 52, Issue 28, Pages 3592-3596Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.05.003
Keywords
Ionic liquid; Reusable; Diorganyl selenides and sulfides; Seleno- and thioesters; Tin chloride; Selenium
Categories
Funding
- TWAS-CNPq
- CNPq
- Capes
- FAPERGS
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The bimetallic reagent Sn(II)/Cu(II) in [bmim]BF4 was efficiently used for the cleavage of diaryl diselenides and disulfides and reacts with a variety of organic substrates, such as organic halides, acid chlorides, and beta-amino mesylates affording the diorganyl selenides and sulfides within very short reaction times, under mild conditions and with excellent yields, using BMIM-BF4 as a reusable solvent. (C) 2011 Elsevier Ltd. All rights reserved.
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