Journal
TETRAHEDRON LETTERS
Volume 52, Issue 24, Pages 3106-3109Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.04.008
Keywords
Bitungolides; Dual specificity VHR phosphatase; Myers'alkylation; Sharpless epoxidation; Ring closing metathesis; Evans' 1,3-anti reduction
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Funding
- UGC
- CSIR New Delhi
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The first total synthesis of (-)-bitungolide E is described. The key steps include a Myers' alkylation, modified Evans' syn aldol-reaction, using Crimmins protocol, Sharpless asymmetric epoxidation and ring-closing metathesis reaction. (C) 2011 Elsevier Ltd. All rights reserved.
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