Journal
TETRAHEDRON LETTERS
Volume 52, Issue 13, Pages 1430-1431Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.11.103
Keywords
C-N formation; Arylboronic acids; Organic azides; Metal-free
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Funding
- National Natural Science Foundation of China [30772652, 90813026]
- National key Tech project for Major Creation of New Drugs [2009ZX09501-010]
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A novel and efficient metal-free carbon-nitrogen bond-forming coupling reaction between arylboronic acids and organic azides is reported. The reaction is fairly general for the preparation of secondary aromatic amines. Furthermore, the reaction is very functional-group tolerant. A possible mechanism is also proposed. (c) 2011 Elsevier Ltd. All rights reserved.
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