Journal
TETRAHEDRON LETTERS
Volume 52, Issue 24, Pages 3133-3136Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.04.029
Keywords
Reduction; Indium; Silane; Ether; Alcohol
Categories
Funding
- Japan Private School Promotion Foundation
- MEXT
- Grants-in-Aid for Scientific Research [21590025] Funding Source: KAKEN
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An InBr3-Et3SiH reducing system was developed to selectively convert aliphatic ketones to a variety of secondary alcohols in moderate to good yields. An initial mixing of InBr3 and PhSiH3 was followed by the addition of aliphatic ketones and a solvent to afford the symmetrical ether derivatives. (C) 2011 Elsevier Ltd. All rights reserved.
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