Journal
TETRAHEDRON LETTERS
Volume 52, Issue 14, Pages 1569-1573Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.01.056
Keywords
Styrenes; Arenes; Dimerization; Palladium; Catalysis
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Funding
- National Natural Science Foundation of China [20376071, 20674063, 20774074]
- Young Teacher Research Foundation of Northwest Normal University [NWNU-LKQN-08-8, NWNU-kjcxgc-03-73]
- Key Laboratory of Eco-Environment-Related Polymer Materials (Northwest Normal University), Ministry of Education
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Pd(acac)(2) catalyzed dimerization of vinylarenes to form dimers under mild condition with excellent yields and stereoselectivities. In particular, the use of TFA highly promoted the activity and selectivity of the dimerization. The studies on mechanism for the reaction displayed clearly that the dimerization of styrenes is 100% atom economic reaction. (C) 2011 Published by Elsevier Ltd.
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