4.4 Article

Gold (I) catalysis of X-H bond insertions

Journal

TETRAHEDRON LETTERS
Volume 51, Issue 41, Pages 5490-5492

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.08.038

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The utility of gold catalysis for carbene X-H bond insertion chemistry is described for the first time, taking advantage of the unique reactivity of sulfoxonium ylides as metal carbene precursors. (C) 2010 Elsevier Ltd. All rights reserved.

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