Journal
TETRAHEDRON LETTERS
Volume 51, Issue 40, Pages 5242-5245Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.07.111
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- Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET)
- Fondo para la Investigacion Cientifica y Tecnologica (FONCyT)
- Secretaria de Ciencia y Tecnologia (Se-CyT-UNC)
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A new 'green' process to obtain trifluoromethoxylated compounds by a gas-phase method has been accomplished. Through it, new 2-substituted-5-(trifluoromethoxy)thiophenes have been obtained in moderate to good yields. Though the reaction occurs in the gas-phase and radicals are involved, an electron transfer mechanism is also postulated to explain the appearance of all detected products. (C) 2010 Elsevier Ltd. All rights reserved.
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