Journal
TETRAHEDRON LETTERS
Volume 51, Issue 33, Pages 4378-4381Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.06.051
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology in Japan [20550033]
- Chiba University
- Grants-in-Aid for Scientific Research [20550033] Funding Source: KAKEN
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Various primary alcohols, particularly benzylic alcohols, could be converted into the corresponding aromatic amides in good yields in a one-pot manner by treatment with molecular iodine in aq. NH(3), followed by reaction with similar to 30% aq H(2)O(2) Similarly, various benzylic halides could be also converted into the corresponding aromatic amides in good yields in a one-pot manner by treatment with molecular iodine in aq NH(3). followed by reaction with similar to 30% act H(2)O. The present reactions Involve the metal-free one-pot oxidative conversion of benzylic alcohols and benzylic halides into the corresponding aromatic amides. respectively (c) 2010 Elsevier Ltd All rights reserved
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